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Serving as the People's Commissar for Welfare in Vladimir Lenin 's government in —, she was a highly prominent woman within the Bolshevik party. She was the first woman to be a cabinet minister, and the first woman ambassador. In , she broke with the Mensheviks and became a member of the Bolsheviks. Following the February Revolution which ousted the tsar , Kollontai returned to Russia.
She supported Lenin's radical proposals and, as a member of the party's Central Committee, voted for the policy of armed uprising which led to the October Revolution and the fall of Alexander Kerensky 's Provisional Government. She was appointed People's Commissar for Social Welfare in the first Soviet government, but soon resigned due to her opposition to the peace treaty of Brest-Litovsk in the ranks of the Left Communists.
In , Kollontai was a leading figure in the foundation of the Zhenotdel , the then-new women's department of the Central Committee that was aimed at improving the status of women in the Soviet Union. She was a champion of women's liberation, and later came to be recognized as a key figure in Marxist feminism.
Kollontai was outspoken against bureaucratic influences over the Communist Party and its undemocratic internal practices. To that end, she sided with the left-wing Workers' Opposition in , but was eventually defeated and sidelined, narrowly avoiding her own expulsion from the party altogether. From on, she was appointed to various diplomatic posts abroad, serving in Norway, Mexico and Sweden. In , she was promoted to the title of ambassador to Sweden.
Kollontai retired from diplomatic service in and died in Moscow in Kollontai's father, General Mikhail Alekseyevich Domontovich [ a ] — , descended from a Ukrainian family that traced its ancestry back to the 13th century [ 3 ] and Daumantas of Pskov.